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Put on gloves to protect your hands and cut the trunk of the ivy plant with pruning shears or loppers. Make the cut 4 inches from the base and allow the ivy to die and dry out for a few days.
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Work the ivy off the chimney using a scraping and gentle pulling technique. Hold a wood scraper almost flat against the brick, scrape loose the ivy stems and gently pull them off. If the chimney goes from ground level to above the house, start at the base of the chimney. For higher, out-of-reach places, use a ladder. Be sure the ladder is on solid, level ground, and have an assistant hold and steady the ladder while you are on it. You may need to cut larger stems with pruning shears first.
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Scrub the chimney with a dry nylon brush to remove the hairy tendrils. For hard-to-remove tendrils, use a stiffer bristled brush and a soapy mixture of water and a mild detergent. The stiff brush can scratch the bricks so test this process on a less visible area.
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Burn off stubborn ivy tendrils and residue with a propane torch as a last resort. Keep the flame moving back and forth and do not concentrate on one area for too long. This could damage the mortar or scorch the surface of the bricks. Test this technique on an inconspicuous spot.
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