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Turn off the gas supply leading to the water heater.
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Press the lock tab under the gas control knob on the front of the Kenmore water heater. Turn the gas control knob to "Off."
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Loosen the screws holding the access door in place. Remove the door.
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Disconnect the thermocouple connections from the gas control assembly with the wrench. Disconnect the pilot supply tube with the wrench.
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Lift the burner assembly out of the Kenmore water heater.
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Remove the screw holding the thermocouple to the burner assembly. Position the new thermocouple into the assembly. Install the screw that holds it in place.
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Replace the burner assembly into the water heater. Connect the thermocouple and pilot supply tube connections.
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Replace the access door. Tighten the screws that hold the door in place. Turn the gas supply on.
Check out this related video from Homesteady on Youtube.